Artificial metalloenzymes for olefin metathesis based on the biotin-(strept)avidin technology.
نویسندگان
چکیده
Incorporation of a biotinylated Hoveyda-Grubbs catalyst within (strept)avidin affords artificial metalloenzymes for the ring-closing metathesis of N-tosyl diallylamine in aqueous solution. Optimization of the performance can be achieved either by chemical or genetic means.
منابع مشابه
Artificial metalloenzymes for enantioselective catalysis based on the noncovalent incorporation of organometallic moieties in a host protein.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 44 شماره
صفحات -
تاریخ انتشار 2011